Microsoft has had DreamSpark for a couple of years and it’s a great resource for student’s to get some software. One of the suites I recommend is Expression Studio. Expression Studio is kind of like Microsoft’s version of Adobe’s Creative Suite.
Instead of Dreamweaver, you can use Expression Web (formerly FrontPage). If you haven’t used this program in a while, it is quite nice, with the same types of features you’d get from the $120 Dreamweaver.